ACS Domain 7: Equilibrium Welcome to your ACS Domain 7: Equilibrium 1. ACS: Equilibrium In a closed system at equilibrium, if the concentration of the reactant is doubled, what happens to the equilibrium constant \( K_c \) for the reaction? \( K_c \) doubles \( K_c \) is halved \( K_c \) remains unchanged \( K_c \) quadruples None 2. ACS: Equilibrium A reaction mixture initially contains 1.00 M A and 2.00 M B. At equilibrium, the concentration of C is 0.50 M. If the reaction is \( A + 2B \rightarrow 3C \), what is the equilibrium constant \( K_c \)? 0.375 0.75 0.125 1.5 None 3. ACS: Equilibrium For the reaction \( 2NO_2(g) \leftrightarrow N_2O_4(g) \), which change would increase the quantity of \( N_2O_4 \) at equilibrium? Increasing the volume of the container Adding a catalyst Increasing the pressure by decreasing the volume Decreasing the temperature None 4. ACS: Equilibrium If the equilibrium constant for a reaction at 300 K is 10 and at 350 K is 25, what can be inferred about the reaction? It is exothermic It is endothermic It is neither exothermic nor endothermic It involves no energy changes None 5. ACS: Equilibrium In which case will the addition of an inert gas at constant volume to the following reaction \( H_2(g) + I_2(g) \leftrightarrow 2HI(g) \) have no effect on the position of equilibrium? If added at constant pressure If added at constant temperature If added at constant volume If added at varying temperature None 6. ACS: Equilibrium What is the effect on the equilibrium position when the temperature is decreased for the exothermic reaction \( 2SO_2(g) + O_2(g) \leftrightarrow 2SO_3(g) \)? Shifts to the right Shifts to the left No shift Shifts unpredictably None 7. ACS: Equilibrium The equilibrium constant for the reaction \( A(g) + B(g) \leftrightarrow C(g) + D(g) \) is 4.0 at a certain temperature. If the initial concentrations of A and B are each 2.0 M, what is the concentration of D at equilibrium? 1.0 M 2.0 M 0.5 M 4.0 M None 8. ACS: Equilibrium The reaction \( PC_5(g) \leftrightarrow PCl_3(g) + Cl_2(g) \) has \( K_p = 0.25 \) at 500 K. If the initial pressure of \( PCl_5 \) is 0.4 atm, what is the total pressure at equilibrium? 0.5 atm 0.6 atm 0.7 atm 0.8 atm None 9. ACS: Equilibrium If the equilibrium constant for a decomposition reaction is less than 1, what can be inferred about the reaction? Products are favored at equilibrium Reactants are favored at equilibrium Neither reactants nor products are favored The reaction does not reach equilibrium None 10. ACS: Equilibrium For a reaction where \( \Delta H = -30 \, kJ/mol \) and \( \Delta S = -80 \, J/mol \cdot K \), what is the effect of increasing temperature on the equilibrium constant? Increases Decreases Remains constant First increases, then decreases None 1 out of 10 Time is Up! Time's up